Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials.
نویسندگان
چکیده
Metal-Organic Framework Materials Omar K. Farha,† Alexander M. Spokoyny,† Karen L. Mulfort,†,‡ M. Frederick Hawthorne,§ Chad A. Mirkin,*,† and Joseph T. Hupp*,† Department of Chemistry and International Institute for Nanotechnology, Northwestern UniVersity, 2145 Sheridan Road, EVanston, Illinois 60208, Chemistry DiVision, Argonne National Laboratory, Argonne, Illinois 60439, and International Institute of Nano and Molecular Medicine, UniVersity of Missouri-Columbia, Missouri 65212
منابع مشابه
Carborane-Based Metal−Organic Framework with High Methane and Hydrogen Storage Capacities
A Cu−carborane-based metal−organic framework (MOF), NU-135, which contains a quasi-spherical para-carborane moiety, has been synthesized and characterized. NU-135 exhibits a pore volume of 1.02 cm/g and a gravimetric BET surface area of ca. 2600 m/g, and thus represents the first highly porous carborane-based MOF. As a consequence of the unique geometry of the carborane unit, NU-135 has a very ...
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 129 42 شماره
صفحات -
تاریخ انتشار 2007